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To make the aioli: Place the red pepper on an open flame or grill.
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Turn to blacken on all sides.
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When fully charred, remove to a bowl and cover with plastic wrap.
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Let pepper cool, until you can handle it comfortably.
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Using your fingers, remove blackened skin to reveal the red color underneath.
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(A paper towel will wipe off what you can't remove with your fingers.)
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Coarsely chop the pepper and place it in the bowl of a food processor.
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Add the yolks, garlic, vinegar, chili paste, and salt to taste.
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Puree until the mixture is homogeneous.
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While the machine is running VERY slowly drizzle in the oil, until incorporated.
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Check the aioli for texture and flavor.
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If it's too thick, add a few drops of water to thin it down, or on the flip side if it's too thin add more oil.
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The desired outcome is a fairly thin aioli.
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Check the flavor and add more salt or chili paste, if desired.
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Refrigerate until ready to use.
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To cook the mussels: In a pot, large enough to accommodate all the mussels, generously coat with olive oil.
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Add the onions and bring to a medium-high heat, stirring frequently.
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Cook the onions until they are very soft and aromatic but have no color.
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Add the garlic, thyme and bay leaf and cook for another 2 to3 minutes.
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Stir to be sure the garlic doesn't burn.
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Add the mussels and stir to coat with the oil.
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Add the wine and cover the pot.
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Steam the mussels for 5 to 6 minutes or until all the shells open.
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If some shells don't open, cook them for a little longer.
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Sometimes the freshest mussels are the most stubborn to open.
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Remove the mussels that don't open after longer cooking.
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When in doubt, throw out.
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While the mussels are steaming, grill or toast the slices of bread.
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Serve the mussels in individual bowls with lots of the juice from the bottom of the pot.
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Generously drizzle each bowl with the aioli.
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Garnish with toast.
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(You may want to have more toasted bread on hand to sop up the delicious liquid!)
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*RAW EGG WARNING
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Food Network Kitchens suggest caution in consuming raw and lightly-cooked eggs due to the slight risk of Salmonella or other food-borne illness.
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To reduce this risk, we recommend you use only fresh, properly-refrigerated, clean, grade A or AA eggs with intact shells, and avoid contact between the yolks or whites and the shell.