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1
Put oven rack in middle position and preheat oven to 325F.
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2
Butter ramekins and dust with sugar, knocking out excess.
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3
Toast chiles in a dry heavy skillet over moderate heat, turning, until fragrant, 1 to 2 minutes.
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4
Discard stems, seeds, and ribs, then soak chiles in hot water to cover until softened, about 30 minutes.
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5
Drain, reserving soaking liquid.
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6
Puree chiles in a mini food processor or a blender, adding 2 to 3 tablespoons soaking liquid as needed to form a paste.
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7
Force paste through a fine-mesh sieve into a bowl and discard solids.
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8
Set aside 1 1/2 tablespoons chile paste and freeze remainder for another use.
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9
Bring juice and 1 cup sugar to a boil in a 1- to 1 1/2-quart saucepan, stirring until sugar is dissolved.
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10
Pour hot syrup over chocolate in a large bowl, stirring until chocolate is melted.
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11
Add butter and stir until melted.
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12
Add eggs 1 at a time, whisking after each addition, then stir in chile paste, flour, and salt.
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13
Divide among ramekins and bake in hot water bath , uncovered, until just firm and top is starting to crust, 50 to 60 minutes.
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14
Transfer ramekins with tongs to a work surface and let stand 2 minutes.
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15
Unmold warm cakes directly onto dessert plates (they will be difficult to move once they adhere).
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16
*Available at Mexican markets, many supermarkets, and Chile TodayHot Tamale (800-468-7377).