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Special equipment: six 6-ounce ramekins
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Preheat the oven to 350 degrees F. Butter the ramekins and then dust with sugar.
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Place the ramekins in a 9-by-13-inch baking dish.
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Place the chocolate chips and the butter in the top of a double boiler set over simmering water.
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Heat until melted, stirring occasionally so that the chocolate chips and butter are well blended and have a smooth, silky texture.
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In a medium bowl, combine the cocoa powder, flour and salt.
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Mix together with a fork.
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Using a hand-held mixer or a whisk, beat the egg whites in a large bowl until stiff peaks form.
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In a medium bowl, beat the egg yolks and sugar with a hand-held mixer or a whisk until the mixture turns pale yellow, about 2 minutes.
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Slowly temper the melted chocolate into the egg yolks and mix until well combined.
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Mix in the milk.
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Add the dry ingredients and blend until fully incorporated.
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With a rubber spatula, fold in the egg whites in three separate additions.
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Fill the prepared ramekins with batter two-thirds of the way up.
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Pour hot water into the baking dish two-thirds of the way up the sides of the ramekins.
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Cover the baking dish tightly with aluminum foil.
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Place in the oven and bake until the cakes are set, 15 to 20 minutes.
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Carefully remove the ramekins from the baking dish and set aside to cool for about 30 minutes.
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Unmold the cakes onto individual plates.
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If the cakes are not releasing from the ramekins, run a small knife or offset metal spatula along the inside of the ramekins.
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Garnish each cake with a dusting of powdered sugar and a sprinkling of orange zest.