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1
In a small heavy saucepan simmer water with 1 cup sugar, stirring until sugar is dissolved.
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2
(Syrup may be made up to this point 2 days ahead and cooled completely before being chilled, covered.)
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3
Preheat oven to 350 F and lightly butter a shallow baking pan.
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4
Coarsely chop hazelnuts.
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5
Stir nuts into syrup and simmer 1 minute.
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6
With a slotted spoon transfer nuts to baking pan, arranging in one layer, and reserve syrup.
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7
Cut butter into pieces.
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8
Bake nuts in middle of oven until golden brown, about 15 minutes.
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9
Immediately add butter to nuts, tossing to coat and separate, and with a spatula transfer nuts to a plate to cool (nuts will crisp as they cool).
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10
(Nuts may be candied 2 days ahead and kept in an airtight container in a cool, dry place.
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11
Reserved syrup may be kept, covered and chilled, 2 days.)
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12
Lightly butter a shallow ovenproof kettle or casserole dish (about 12 by 2 1/2 inches).
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13
With a sharp knife trim a very thin slice from bottom of each pear to enable pears to stand upright.
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14
Dip and roll each pear in reserved syrup to coat completely.
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15
Transfer pears as coated to kettle, standing them upright, and sprinkle with remaining 1/4 cup sugar.
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16
Add liqueur, lemon juice, and vanilla to remaining reserved syrup and pour down side of kettle or casserole.
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17
Roast pears, uncovered, in middle of oven until undersides are tender when pierced with a knife, about 30 minutes.
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18
Arrange pears on a serving platter.
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19
Spoon syrup around pears and sprinkle with candied nuts.
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20
Serve pears warm or at room temperature.