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1
Bring water and 2 1/2 cups sugar to a boil in a 4-quart heavy saucepan, stirring until sugar is dissolved.
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2
Add quinces and cook at a bare simmer, partially covered, turning occasionally, until tender when pierced near core with a fork (core will remain hard), about 45 minutes to 1 hour.
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3
Cool quinces, uncovered, in syrup, about 1 1/2 hours, then transfer with a slotted spoon to a plate.
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4
While quinces are cooling, simmer prunes in Armagnac in a small saucepan, uncovered, until plump, about 10 minutes, then cool.
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5
Drain prunes in a sieve set over a bowl, reserving Armagnac.
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6
Set aside 6 prune halves and finely chop remainder.
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7
Cook butter and remaining 2 tablespoons sugar in a 2-quart heavy saucepan over moderate heat, stirring, until sugar is dissolved, about 5 minutes.
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8
Carefully add 1/4 cup Grand Marnier and 6 tablespoons reserved Armagnac.
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9
(Mixture may ignite.
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10
If so, let flames burn out.)
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11
Simmer until slightly syrupy, about 2 minutes.
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12
Transfer Grand Marnier sauce to a measuring cup.
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13
Core quinces using a large melon-ball cutter and a sharp small knife.
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14
Scoop 1 tablespoon flesh from center of each quince half and transfer to a bowl.
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15
Scrape seeds from vanilla bean with sharp small knife into bowl with quince flesh, reserving pod.
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16
Stir in chopped prunes and remaining tablespoon Grand Marnier.
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17
Transfer quince halves to a shallow baking pan and spoon filling into cavity of each, then top with prune halves.
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18
Drizzle each quince half with 1 teaspoon Grand Marnier sauce, reserving remaining sauce.
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19
Cut vanilla pod halves crosswise into thirds and stick 1 piece into filling of each quince.
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20
Preheat broiler.
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21
Scrape seeds from vanilla bean with sharp small knife into a shallow bowl, then whisk together with cream, eggs, sugar, and Grand Marnier.
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22
Dip brioche slices into batter 1 at a time, letting them soak 1 minute on each side.
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23
Transfer to a buttered shallow (1-inch-deep) flameproof baking pan.
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24
Broil 4 to 6 inches from heat until golden brown, about 2 minutes on each side.
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25
Transfer brioche to a cutting board and halve diagonally, then return to baking pan.
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26
Preheat oven to 400F.
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27
Bake quinces in upper third of oven until heated through, about 10 minutes.
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28
At the same time, reheat brioche in lower third of oven until hot, about 6 minutes.
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29
Divide quinces and brioche among 6 plates and drizzle remaining Grand Marnier sauce over and around quinces.
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30
Spoon creme frai:che on top.