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Preheat oven to 350 degrees F.
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To make the white chocolate cake: Melt chocolate in metal bowl over pot of simmering water.
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Remove from heat and stir.
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Using a tabletop mixer with whip attachment, beat butter and sugar until light and fluffy.
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Add eggs in 1 minute intervals, mixing well with each addition.
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Stir dry ingredients together in large bowl.
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Alternately mix dry ingredients and milk into egg mixture.
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Scrape sides and bottom of bowl and beat with each addition 1 minute.
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Stir in chocolate and pour into 2 greased and lightly floured 8 by 1 1/2-inch round pans.
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Place in 350 degrees F oven and bake 30 to 35 minutes or until golden brown and firm to touch.
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Cool.
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Store on plate until ready to assemble cake.
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To make the devil's food cake: Using tabletop mixer with whip attachment, mix dry ingredients well.
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Slowly add egg, oil, milk, and coffee, scraping sides and bottom between each addition.
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Continue to mix until thoroughly incorporated and smooth.
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Grease and flour 2 by 8 by 1 1/2-inch pans and pour batter in each 1/4-inch from rim.
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Place pans in 350 degrees F oven to bake 25 to 30 minutes.
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Cakes should be firm to the touch and moist.
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Cool cakes on rack and transfer to plates to assemble.
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To make the white chocolate buttercream: Boil sugar and water in sauce pot until it registers 335 degrees F on a candy thermometer or when a soft ball of sugar forms when a teaspoon of syrup is placed in ice-water.
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Beat whites in bowl of table top mixer with whip attachment on high speed until firm peaks form.
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Slowly and carefully, pour hot syrup into the whites.
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Continue to whip meringue until cool.
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Add butter to meringue and thoroughly mix.
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Stir in chocolate and vanilla.
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To make the white chocolate decor: Slightly temper chocolate until surface is soft, but not melted.
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Using a sharp knife working away from you, carefully run it through the chocolate, forming 3-inch chocolate sticks.
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For best results, make sure chocolate is soft but not tacky.
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Make approximately 25 sticks.
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Soften remaining chocolate slightly and use a vegetable peeler to form medium size curls.
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Place chocolate stick and shavings on a tray in the refrigerator until ready to assemble cake
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To assemble: Place white chocolate cake layer on 9-inch plate.
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Using a serrated knife, level tops of cake by trimming off the dome.
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Discard excess cake.
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Spread 3/4 cup of butter cream over top of cake.
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Repeat next 3 layers starting with devils food cake and ending with white.
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Frost tops and sides of cake evenly with remaining buttercream.
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Coat sides and top of cake evenly with white chocolate shavings.
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Arrange the chocolate sticks into the tops of the cake sticking in from edges to center on 45 degree angle.
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Sprinkle additional shavings over sticks to fill in voids.
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Cut into 12 equal pieces and serve.