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COOKIES:.
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Whisk the flour, cocoa, baking powder, cinnamon, orange zest, and salt together in a large bowl.
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In another medium bowl, briskly whisk the eggs, sugar and melted butter together until smooth and evenly combined.
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Make a well in the center of the dry ingredients and pour in the egg mixture.
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Gradually whisk the liquid into the flour to make a thick batter.
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When the pizzelle batter starts to clump up in the whisk, switch to a rubber spatula to finish mixing it together.
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(If you have a large pastry bag, put a big round tip in it, and fill with the pizzelle batter.)
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Preheat a pizzelle iron until a drop of water sizzles on the hot surface, about 10 minute
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Lightly spray the hot surface with nonstick cooking spray.
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Pipe or spoon about a tablespoon of the batter into the center of each cookie imprint.
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Close the iron and cook until whiffs of steam comes from the iron, about 30 to 45 seconds.
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Open and remove cookie from the iron, cool on a rack.
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Repeat with remaining batter.
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FILLING:.
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Put the chocolate and butter in a microwave safe bowl.
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Cover and microwave on medium power until soft and melted, about 3 minutes depending on the power of your oven; stir until smooth.
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Alternatively, put the chocolate in a heatproof bowl.
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Bring a saucepan filled with 1-inch or so of water to a very slow simmer; set the bowl on the pan (without touching the water).
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Stir occasionally until melted and smooth. Stir in mint extract.
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To serve pipe a tablespoon of the mint filling into the center of half the cookies.
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Top with another cookie and press to make a sandwich.
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Serve now or keep tightly covered for up to 1 week.