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1
Preheat oven to 325 F. Line 17 1/4x11 1/2x1-inch baking sheet with parchment.
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2
Bring sugar, butter and water to boil in heavy large saucepan over medium heat, stirring until sugar dissolves.
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3
Reduce heat to low.
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4
Add chocolate; stir until smooth.
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5
Whisk eggs and vanilla in large bowl to blend.
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6
Gradually whisk in hot chocolate mixture.
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7
Mix in flour, baking soda and salt, then nuts.
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8
Spread butter over prepared sheet.
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9
Bake until toothpick inserted into center comes out clean, about 20 minutes.
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10
Cool completely.
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11
Freeze until firm.
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12
Cut around brownie to loosen.
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13
Turn out onto work surface.
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14
Peel off parchment.
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15
Trim brownie to 16x10-inch rectangle; cut in half crosswise, making two 8x10-inch rectangles.
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16
Place 1 rectangle on baking sheet.
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17
Cover brownie with ice cream.
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18
Freeze until slightly firm.
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19
Lightly score top of remaining brownie in half lengthwise, then score across, in 2-inch sections, making 10 2x4-inch rectangles.
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20
Press scored brownie atop ice cream, scored side up.
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21
Freeze until ice cream is firm, at least 4 hours.
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22
Cut brownie along marked lines into 10 sandwiches.
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23
( Can be made 2 weeks ahead.
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24
Wrap tightly; keep frozen.)
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25
Stir chocolate and coffee in saucepan over low heat until smooth.
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26
Add liquer.
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27
(Can be made 1 week ahead.
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28
Cover; chill.
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29
Rewarm before serving.)
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30
Serve sandwiches with sauce.