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1
Position a rack in the lower third of the oven and preheat the oven to 325u00b0F Line the bottom and sides of an 8x8-inch square baking pan with parchment paper or foil, leaving an overhang on two opposite sides.
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2
Spray the pan and lining with cooking spray.
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3
Combine the butter, sugar, cocoa, and salt in a medium heatproof bowl and set the bowl in a wide skillet of barely simmering water.
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4
Stir occasionally until the butter is melted and the mixture is smooth, though it will appear somewhat gritty.
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5
Remove the bowl from the skillet and set aside briefly until the mixture is only warm, not at all hot.
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6
Stir in the vanilla with a wooden spoon.
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7
Add the eggs one at a time, stirring well after each one.
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8
When the batter looks thick, shiny, and well-blended, add the flour and stir until all the streaks of flour disappear, then beat vigorously for 40 more strokes with the wooden spoon or a rubber spatula.
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9
Stir in the nuts, if using. Spread evenly in the prepared pan.
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10
Bake until a toothpick plunged into the center emerges slightly moist with batter, about 25 minutes.
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11
Let cool completely on a wire rack.
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12
Set the pan in the freezer for 10 minutes (it will make for clean cutting of the brownies).
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13
Lift up the ends of the parchment or foil liner, and transfer the brownies to a cutting board.
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14
Cut into 16 squares.