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1
In a mixing bowl, whisk flour, baking powder, and salt until uniform; set aside.
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2
Add 4 ounces white chocolate and all the butter in the top of a double boiler set over simmering water.
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3
Stir constantly until half the chocolate and butter is melted.
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4
Remove the top of the double boiler; continue stirring, away from the heat, until the mixture is smooth; cool for 10 minutes.
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5
In a large mixing bowl, whisk the egg and sugar until thick and pale yellow (approx 2 minutes).
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6
Whisk in the cooled chocolate mixture until smooth; whisk in the milk and vanilla.
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7
Use a wooden spoon and stir in the remaining chopped white chocolate.
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8
Stir in flour mixture just until moistened.
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9
Fill muffin tins that have been sprayed with nonstick cooking spray, 3/4 full.
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10
Bake in a 375u00b0F oven for 20 minutes OR until muffins are browned with sightly rounded tops and pick comes out clean.
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11
Set pan on a wire rack to cool for 10 minutes.
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12
Turn muffins out of pan; cool on wire rack for 5 minutes.
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13
If storing or freezing muffins, cool completely before sealing in airtight container or in freezer-safe plastic bags.
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14
Alternative--White Chocolate Orange Muffins: add 2 teaspoons orange extract or 1/2 teaspoon orange oil with the vanilla.