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Heat oven to 350 degrees F.
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Line 13x9-inch pan with foil, with ends of foil extending over sides.
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Grease foil.
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Microwave 3/4 cup (1-1/2 sticks) butter and unsweetened chocolate in large microwaveable bowl on HIGH 2 min.
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or until butter is melted.
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Stir until chocolate is completely melted.
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Add granulated sugar, 4 eggs, 2 Tbsp.
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coffee granules and 1 tsp.
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vanilla; mix well.
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Stir in flour until well blended; pour into prepared pan.
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Bake 25 min.
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Meanwhile, microwave brown sugar and 1/4 cup (1/2 stick) of the remaining butter in small microwaveable bowl 1 min.
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or until butter is melted.
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Add 1 Tbsp.
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of the remaining coffee granules and remaining egg and vanilla; mix well.
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Chop 6 oz.
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semi-sweet chocolate.
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Add to brown sugar mixture with nuts; mix well.
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Spread nut mixture over warm brownies.
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Bake 20 min.
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or until toothpick inserted in center comes out with fudgy crumbs.
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(Do not overbake.)
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Cool completely.
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Microwave remaining semi-sweet chocolate, butter and coffee granules in microwaveable bowl 1 min.
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or until butter is melted.
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Stir until chocolate is completely melted and mixture is well blended.
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Drizzle over brownies; let stand until firm.