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1
Scrape seeds from vanilla bean into cream in a 2-quart heavy saucepan, then add pod and bring to a simmer over moderate heat.
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2
Remove from heat, then steep, covered, 20 minutes.
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3
Discard pod.
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4
Preheat oven to 325F.
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5
Whisk together yolks, sugar, and a pinch of salt, then add hot cream in a slow stream, whisking constantly.
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6
Pour through a fine sieve into glass loaf pan.
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7
Cover pan with foil and bake custard in a hot water bath until set but with center still slightly wobbly, about 1 hour.
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8
Remove foil and cool custard in pan on a rack, then chill, covered, until firm, at least 4 hours.
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9
Scrape seeds from vanilla bean into juice in cleaned 2-quart heavy saucepan, then add pod and sugar.
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10
Bring to a boil over moderately high heat, stirring until sugar is dissolved, then boil until reduced to about 1 1/4 cups, about 20 minutes.
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11
Remove from heat, then discard pod and stir in Grand Marnier.
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12
Cool to room temperature.
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13
Preheat oven to 375F.
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14
Chop enough pistachios to measure 2 tablespoons.
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15
Pulse remaining nuts with regular granulated sugar in a food processor until finely ground.
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16
Add flour and salt and pulse to combine.
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17
Add milk, butter, and eggs and blend until just combined.
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18
Pour batter into well-buttered popover cups, filling them two-thirds full.
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19
Bake in lower third of oven until popovers are puffed and well browned, about 40 minutes.
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20
Cut a 1/2-inch slit in top of each popover and bake 10 minutes more.
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21
Immediately turn popovers out onto rack to cool.
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22
Cut off tops of cooled popovers and arrange in a baking dish.
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23
Brush tops with some syrup and heat in oven until warm, about 3 minutes.
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24
While tops are heating, fill bottoms of popovers with custard.
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25
Sprinkle 1 teaspoon superfine sugar evenly over each custard, then move blowtorch flame evenly back and forth just over sugar until sugar is melted and caramelized.
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26
Transfer popovers with tops to plates and spoon some syrup around each.
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27
Sprinkle with chopped nuts.