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1
Whisk 1/2 cup kosher salt and 1/2 cup sugar into 8 cups of water (may need to be divided into two bowls) until salt and sugar dissolve.
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2
Add pork chops and refrigerate for at least 8 hours, could be as long as overnight.
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3
Blanch pearl onions in large saucepan of boiling water for 1 minute.
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4
After one minute, remove the onions from the water and drain.
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5
Allow to cool slightly and peel them.
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6
Heat 1/4 cup of oil in a large skillet over medium high heat.
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7
Add onions and cook them until tender and browned in spots, turning occasionally (8-10 minutes).
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8
Move onions and oil to a medium-sized bowl.
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9
Increase heat in the skillet to high and heat 1 tablespoon of oil and add 1/2 of the red onion and 1/2 of the peppers and saute until softened, about 5 minutes.
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10
Add crushed red pepper and 1 1/2 teaspoons sugar.
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11
Season to taste with salt and pepper and turn heat to low and simmer for 10 minutes.
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12
Stir in 1/2 of the reserved pearl onions and 1/2 of the pickled cherry peppers.
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13
Stir to combine then remove the mixture from the pan.
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14
Place it in a tupperware container if you plan on serving it later.
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15
Or keep it warm until your chops are ready.
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16
Repeat this process with the second half of peppers, red onions, pearl onions and cherry tomatoes.
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17
Add to tupperware with the first half and refrigerate it if you are making this in advance.
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18
Or keep it warm until your chops are ready.
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19
When ready to serve, prepare your grill to high heat.
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20
Remove pork chops from brine and pat dry.
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21
Brush chops with oil and season with pepper.
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22
Grill about 5 minutes per side.
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23
Place one pork chop on a plate and spoon bell pepper mixture over.
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24
Drizzle with balsamic vinegar and serve!