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1
For the pears: Lightly butter a 9-inch round cake pan, line the bottom with parchment paper, and butter the paper.
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2
Put the butter, brown sugar, and lemon zest and juice in a large skillet.
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3
Cook over medium heat, stirring, until melted.
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4
Add the pears, cover, and simmer, turning once, until the pears are soft and juicy, about 4 minutes.
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5
Pour the pears and their syrup into a strainer set over a saucepan.
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6
Set the syrup and 1 pear quarter aside.
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7
Arrange remaining pears in the prepared pan, stem ends toward center, rounded sides down, and 1/4-inch from the side.
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8
Chop reserved pear and use just enough to fill center.
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9
For the cake: Set a rack in the middle of the oven and preheat to 350 degrees F.
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10
Scald milk in a small saucepan; keep warm.
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11
Whisk flour with almonds, baking soda, baking powder, salt, cinnamon, and cloves.
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12
Beat butter with an electric mixer at medium speed until smooth, about 2 minutes.
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13
Increase speed to medium-high and gradually add granulated sugar; continue beating until mixture is light and fluffy, about 4 minutes, scraping down sides of bowl.
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14
Add cocoa powder and vanilla and beat 1 minute.
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15
While mixing at medium-low speed, add eggs 1 at a time, beating well after each addition.
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16
While mixing slowly, add the flour mixture in 4 additions; turn off the mixer and fold in the hot milk with a rubber spatula.
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17
Spread the batter over the pears, taking care not to disturb them.
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18
Tap the pan lightly on the counter to settle the batter.
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19
Bake until a toothpick inserted in the center comes out clean, about 50 minutes.
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20
Cool cake in the pan on a rack for 20 minutes, then invert the cake onto a serving plate.
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21
Cool briefly, carefully peel the parchment paper from the top, and then cool completely.
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22
To finish the cake: Boil the reserved pear syrup until slightly thick and lightly brush the top of the cake with syrup.
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23
Whisk a few tablespoons of cocoa powder with an equal amount of confectioners' sugar, and sift over the cake; serve.