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For the cake:.
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Preheat oven to 350.
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Grease and line two 9-inch-round baking pans with wax paper.
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Microwave baking bar in small, uncovered, microwave-safe bowl on HIGH (100%power) for 1 minute.
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Stir.
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Sections may retain some of their original shape.
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If necessary, microwave at additional 10-to-15-second intervals,stirring just until smooth.
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Cool to room temperature.
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Combine flour, baking soda and salt in small bowl.
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Beat brown sugar, butter, eggs, instant coffee and vanilla extract in large mixer bowl for 3 minutes.
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Gradually add melted chocolate and continue beating for an additional minute.
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Beat flour mixture into creamed mixture alternately with buttermilk.
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Pour into prepared pans.
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Bake for 22-38 minutes or until wooden pick inserted in center comes out clean.
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Cool in pans on wire racks for 10 minutes.
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Run knife around edges of cakes.
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Invert onto wire racks; remove wax paper.
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Cool completely.
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Brush cakes with Coffee Glaze over cake layers.
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Spread Mocha Buttercream frosting between layers and over top and sides of cake.
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For Coffee Glaze:.
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Microwave granulated sugar, water and instant coffee in small, uncovered, microwave-safe bowl on HIGH (100% power) for 30 seconds.
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Stir until sugar and coffee are dissolved.
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For Mocha Buttercream Frosting:.
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Microwave baking bar in small, uncovered, microwave-safe bowl on HIGH (100%) power for 1 minute; Stir.
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Sections may retain some of their original shape.
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If necessary, microwave at 10-to-15-second intervals, stirring just until smooth.
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Cool to room temperature.
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Dissolve instant coffee in milk in glass measure.
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Beat butter, vanilla extract and salt in large mixer bowl for 3 minutes.
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Beat in melted chocolate until blended, scraping occasionally.
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Gradually beat in powdered sugar until light and fluffy.
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Beat in coffee mixture, 1 tablespoons at a time, until desired spreading consistency.