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1
For the cupcakes: Preheat the oven to 350 degrees F and position a rack in the middle of the oven.
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2
Line one 12-cup standard muffin tin with cupcake liners.
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3
Combine the butter, cocoa, coffee and 1/3 cup water in a microwave-safe bowl, cover with plastic wrap and microwave on high until the butter melts, about 1 minute.
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4
Whisk to combine.
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5
Meanwhile, whisk the flour, light brown sugar, cinnamon, ancho powder, baking powder, baking soda, salt and cayenne in a large bowl.
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6
Beat the sour cream with the eggs and vanilla in a small bowl.
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7
Whisk the hot cocoa mixture into the dry ingredients.
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8
Stir in the sour cream mixture just to combine; don't overmix.
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9
Fill each cupcake liner about two-thirds of the way full with batter.
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10
Bake until a toothpick inserted in the center of the cake comes out clean, 18 to 20 minutes.
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11
Cool the cupcakes on a rack in the tin for 10 minutes, and then remove from the tin.
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12
Cool on the rack completely.
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13
For the glaze: Combine the butter, chocolate, honey, ancho powder and salt in a small microwave-safe bowl and cover with plastic wrap.
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14
Microwave on high until the butter and most of the chocolate is melted, about 1 minute.
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15
Whisk until smooth and let sit to cool, 15 to 20 minutes.
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16
Dip the top of each cupcake in the glaze.
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17
Garnish with chiles and dragees if desired.