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Preheat oven to 350 degrees.
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Prepare 9 by 13 inch baking pan by greasing with butter or spraying with a cooking spray (such as Pam).
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Melt butter in a large saucepan.
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Over low heat add unsweetened chocolate and stir until chocolate is melted.
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Remove from heat, mix in sugar (in saucepan).
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Add eggs and vanilla, stir until incorporated.
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Add flour, baking powder, and salt and stir just till flour is mixed in.
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Gently stir in white chocolate.
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Spread mixture in prepared pan.
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Bake 30 to 35 minutes just until brownies begin to pull away from the sides.
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Remove from oven and let cool completely.
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While brownies are baking, prepare ganache topping.
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Over low heat in a medium saucepan, bring heavy cream to the boil.
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Remove from heat and add chocolate chips.
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Let sit for a few minutes to melt chocolate.
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Stir until all chocolate is melted.
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Let mixture cool and thicken, stirring occasionally for about 20 to 30 minutes.
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Spread chocolate ganache over completely cooled bownies.
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Press chopped, toasted pecans into the ganache.
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Let ganache harden and then cut into squares and then into triangles.
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Carefully remove from pan and serve on a garnished plate.
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The recipes for this program, which were provided by contributors and guests who may not be professional chefs, have not been tested in the Food Network's kitchens.
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Therefore, the Food Network cannot attest to the accuracy of any of the recipes.