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In the top of a double boiler or in a stainless-steel mixing bowl set over a pan of simmering water so that the bottom of the bowl does not touch the water, melt the chocolate.
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Set aside to cool.
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Preheat the oven to 350F.
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Grease and flour three 8-inch cake pans.
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In a large bowl, sift the flour with the baking soda and salt; set aside.
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In the work bowl of an electric stand mixer fitted with the paddle attachment, or in a large mixing bowl with a handheld mixer, place the butter, brown sugar, eggs, and vanilla and beat on high speed until lightened in color, about 3 minutes, scraping down the sides occasionally.
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Reduce the speed to low and beat in the chocolate.
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Add the flour mixture in 3 parts alternately with the buttermilk in 2 parts, starting and ending with the flour.
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Beat in the water until smooth.
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Pour into the prepared pans.
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Bake until the cake pulls away from the sides and a toothpick inserted into the center comes out clean, 30 to 35 minutes.
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Let the cake layers cool in the pans on wire racks for 5 minutes.
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Run a thin knife around the outside and turn out onto racks.
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Peel off the paper.
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Flip them over to completely cool right-side up on the racks.
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If not assembling right away, cover the layers in plastic wrap and store at room temperature for 1 day.
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Meanwhile, prepare the frosting: In the top of a double boiler or in a stainless-steel mixing bowl set over a pan of simmering water so that the bottom of the bowl does not touch the water, melt the chocolate.
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Set aside to cool.
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In the work bowl of an electric stand mixer fitted with the paddle attachment, or in a large mixing bowl with a handheld mixer, place the cooled, melted chocolate, the sugar, and the hot water.
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Beat on medium speed until smooth.
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Add the egg, butter, and vanilla.
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Continue beating until the frosting is thick and fluffy and mounds beautifully on a spoon, 2 to 3 minutes.
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23
When ready to fill and frost the cake, hold a serrated knife horizontally and use a gentle sawing motion to shave the domed top off each layer.
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24
Fill and frost the cake, using a crumb coat (page 202) if you have time.
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25
Store in a tightly covered container in the refrigerator for up to 2 days; let stand at room temperature for 30 minutes before serving.
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26
If the percentages you sometimes see on bars of chocolate seem baffling, just know this: They refer to the percentage of cocoa solids and cocoa butter in the chocolate.
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This varies from brand to brand, but generally semisweet chocolate is about 50 percent cocoa, and bittersweet is 60 to 70 percent cocoa.
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Always use a good-quality chocolate in chocolate dessertsit will usually determine how good your end result is!